An efficient tetrazine photoluminescent layer used for organic solar cells down shifting

Ourida Ourahmoun (1, 2) , Thierry Trigaud (2) , Bernard Ratier (2) , Mohammed Said Belkaid (1) , Laurent Galmiche (3) , Pierre Audebert (3)

1 UMMTO - Université Mouloud Mammeri [Tizi Ouzou]
2 XLIM-RFEI - RF-ELITE : RF-Electronique Imprimée pour les Télécommunications et l'Energie
3 PPSM - Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires

This work reports a new material used as photo luminescent layer in inverted organic solar cells. We have studied the fluorescence and the optical properties of tetrazine molecules included in the layer. The molecules are used at a small to average concentration in a matrix of polymers such as PMMA or Polystyrene, and contain an UV-absorbing moiety acting as an antenna, attached to the yellow-emitting tetrazine. It is therefore able to achieve the down conversion of otherwise useless UV photons into useful yellow photons. The results show that the performances of the inverted organic photovoltaic cells are enhanced by use the luminescent down shifting layer, especially in the UV range.

Mots clés: Inverted organic cells; Fluorescence; down shifting; S-tetrazine

Domaines: Sciences de l'ingénieur [physics]; Energie électrique

Ourida Ourahmoun, Thierry Trigaud, Bernard Ratier, Mohammed Said Belkaid, Laurent Galmiche, et al.. An efficient tetrazine photoluminescent layer used for organic solar cells down shifting. Synthetic Metals, 2017, 234, pp.106 - 110. ⟨10.1016/j.synthmet.2017.09.004⟩. ⟨hal-01704772⟩