Dynamical Molecular Disorder and Diffuse Scattering in an Alkane/Urea Incommensurate Inclusion Compound

Ronan Lefort (1) , B. Toudic (1) , J. Etrillard (1) , F. Guillaume , P. Bourges (2) , R. Currat (3) , T. Breczewski

1 GMCM - Groupe matière condensée et matériaux
2 LLB - UMR 12 - Laboratoire Léon Brillouin
3 ILL - Institut Laue-Langevin

The diffraction pattern of n-alkane/urea inclusion compounds is known to contain a broad diffuse scattering related to the molecular form factor of the alkane species, indicating individual rotational and/or translational disorder of these molecules. Inelastic coherent neutron scattering reveals for the first time the entirely dynamical character of the alkane molecular disorder around room temperature. This observation fully agrees with a recent model of the coherent scattering cross section of totally uncorrelated motions. In the ordered phase this diffuse scattering remains, but elastic, and very low energy molecular vibrational modes are evidenced. These observations are discussed in relation with previous incoherent neutron scattering results.

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Ronan Lefort, B. Toudic, J. Etrillard, F. Guillaume, P. Bourges, et al.. Dynamical Molecular Disorder and Diffuse Scattering in an Alkane/Urea Incommensurate Inclusion Compound. The European Physical Journal B: Condensed Matter and Complex Systems, 2001, 24(1), pp.51-57. ⟨10.1007/s100510170021⟩. ⟨hal-00090317⟩