Reversible P–C bond formation for saturated α-aminophosphine ligands in solution: stabilization by coordination to Cu(I)
Résumé
The saturated α-aminophosphine ligands containing a secondary amine function Ph2PCH(R′)NHR″ establish a solution equilibrium with Ph2PH and R′CH2NR″ and are stabilized by electron-withdrawing substituents R′ and R″ and by coordination of the phosphorous donor to Cu(I).
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142-10.1002-(SICI)1521-3765(19990503)55-Accepted.pdf (451.39 Ko)
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