Crystalline and Electronic Structures of the Al(1+ x)V2Sn(2-x) ( x = 0.19) Intermetallic Compound

Pascal Boulet (1) , Marie-Cécile de Weerd (1) , Emilie Gaudry (2) , Sašo Šturm , Jaafar Ghanbaja (1) , Sylvie Migot (1) , Emmanuelle de Clermont Gallerande (2) , Mostafa Oulfarsi , Jean-Marie Dubois (1) , Vincent Fournée (1) , Julian Ledieu (1)

1 IJL - Institut Jean Lamour
2 IMPMC - Institut de minéralogie, de physique des matériaux et de cosmochimie

A new ternary phase with a composition Al 1+x V 2 Sn 2-x (x=0.19) has been found during the investigation of the Al-V-Sn ternary system. Single crystal X-ray diffraction measurements reveal that this ternary phase crystallizes with an orthorhombic structure with a = 5.5931(1) Å, b = 18.8017(5) Å and c = 6.7005(2) Å (Space group Cmce). This

Domaines: Science des matériaux [cond-mat.mtrl-sci]; Matériaux

Pascal Boulet, Marie-Cécile de Weerd, Emilie Gaudry, Sašo Šturm, Jaafar Ghanbaja, et al.. Crystalline and Electronic Structures of the Al(1+ x)V2Sn(2-x) ( x = 0.19) Intermetallic Compound. Inorganic Chemistry, 2019, 59 (1), pp.360-366. ⟨10.1021/acs.inorgchem.9b02545⟩. ⟨hal-02497735⟩