HCN dimers: Photoelectron spectrum of iminoacetonitrile

R.A. Evans , Sylvie Lacombe-Lhoste (1) , Maryse Simon , G. Pfister-Guillouzo , C. Wentrup

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

The photoelectron spectrum of iminoacetonitrile (HN=CHCN), obtained by gentle pyrolysis of the sodium salt of 1-cyanoformamide tosylhydrazone at 200°C, is reported. The first (vertical) ionization potentials are 11.60, 12.34, 13.09, 13.84, and 14.51 eV. These are compared with those of N-cyanomethanimine (CH2=N-CN). © 1992 American Chemical Society.

Domaines: Chimie; Matériaux; Chimie organique

R.A. Evans, Sylvie Lacombe-Lhoste, Maryse Simon, G. Pfister-Guillouzo, C. Wentrup. HCN dimers: Photoelectron spectrum of iminoacetonitrile. The Journal of physical chemistry, 1992, 96 (12), pp.4801--4804. ⟨hal-01582246⟩