A cyclic peptide-based redox-active model of rubredoxin.

Aurélie Jacques (1) , Martin Clémancey (1) , Geneviève Blondin (1) , Vincent Fourmond (2) , Jean-Marc Latour (1) , Olivier Sénèque (1)

1 LCBM - UMR 5249 - Laboratoire de Chimie et Biologie des Métaux
2 BIP - Bioénergétique et Ingénierie des Protéines

A model of rubredoxin based on a cyclic peptide with a linear tail is presented. This model reproduces almost perfectly the fold, the spectroscopic characterizations and the redox activity of rubredoxins.

Domaines: Chimie de coordination

Aurélie Jacques, Martin Clémancey, Geneviève Blondin, Vincent Fourmond, Jean-Marc Latour, et al.. A cyclic peptide-based redox-active model of rubredoxin.. Chemical Communications, 2013, 49 (28), pp.2915-7. ⟨10.1039/c3cc40517f⟩. ⟨hal-01069592⟩