Terpyridine complexes of first row transition metals and electrochemical reduction of CO₂ to CO.
Résumé
Homoleptic terpyridine complexes of first row transition metals are evaluated as catalysts for the electrocatalytic reduction of CO2. Ni and Co-based catalytic systems are shown to reduce CO2 to CO under the conditions tested. The Ni complex was found to exhibit selectivity for CO2 over proton reduction while the Co-based system generates mixtures of CO and H2 with CO : H2 ratios being tuneable through variation of the applied potential.
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Rev_Accepted Manuscript Copy_Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO.pdf (785.06 Ko)
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Rev_SI_Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO.pdf (2.84 Mo)
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