Oxygen diffusion coefficient and oxygen exchange coefficient of BIMEVOX.10 (ME=Cu, Co) ceramic membranes

M. Guilledo (1) , Jean-Marc. Bassat (2) , Jacques Fouletier (1) , Laurent Dessemond (1) , P. del Gallo (3)

1 LEPMI - Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
3 CRCD - Centre de Recherche Claude Delorme [Jouy-en-Josas]

The 18O/16O Isotope Exchange Depth Profile technique (IEDP) was applied to BIMEVOX.10 (ME=Cu, Co) materials to determine their oxygen exchange coefficients and bulk oxygen tracer diffusion coefficients. These results are compared to the exchange current densities obtained from current–voltage curves and bulk conductivity determined by impedance spectroscopy...

Keywords: BIMEVOX; Copper; Cobalt; Oxygen diffusion; Oxygen exchange

Domains: Material chemistry

M. Guilledo, Jean-Marc. Bassat, Jacques Fouletier, Laurent Dessemond, P. del Gallo. Oxygen diffusion coefficient and oxygen exchange coefficient of BIMEVOX.10 (ME=Cu, Co) ceramic membranes. Solid State Ionics, 2003, 164 (1-2), pp.87-96. ⟨10.1016/S0167-2738(03)00306-0⟩. ⟨hal-00164170⟩