A Chimeric NiFe Hydrogenase Heterodimer to Assess the Role of the Electron Transfer Chain in Tuning the Enzyme’s Catalytic Bias and Oxygen Tolerance

Andrea Fasano (1) , Chloé Guendon (1) , Aurore Jacq-Bailly (1) , Arlette Kpebe (1) , Jérémy Wozniak (1) , Carole Baffert (1) , Melisa Del Barrio (1) , Vincent Fourmond (1) , Myriam Brugna (1) , Christophe Léger (1)

1 BIP - Bioénergétique et Ingénierie des Protéines

Mots clés: hydrogenase artificial enzyme orange protein molybdenum-copper clusters; hydrogenase; artificial enzyme; orange protein; molybdenum-copper clusters

Domaines: Chimie analytique

Andrea Fasano, Chloé Guendon, Aurore Jacq-Bailly, Arlette Kpebe, Jérémy Wozniak, et al.. A Chimeric NiFe Hydrogenase Heterodimer to Assess the Role of the Electron Transfer Chain in Tuning the Enzyme’s Catalytic Bias and Oxygen Tolerance. Journal of the American Chemical Society, 2023, 145 (36), pp.20021-20030. ⟨10.1021/jacs.3c06895⟩. ⟨hal-04284474⟩