Raman bands of double-wall carbon nanotubes: comparison with single- and triple-wall carbon nanotubes, and influence of annealing and electron irradiation

Pascal Puech (1) , Emmanuel Flahaut (2) , Ayman Bassil (1) , Thomas Juffmann (1) , François Beuneu (3) , Wolfgang Bacsa (1)

1 Laboratoire Physique des Solides de Toulouse
2 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux
3 LSI - Laboratoire des Solides Irradiés - Irradiated Solids Laboratory

We compare the G and G2D bands of single-, double- and triple-wall carbon nanotubes (CNTs). We observe that the band shape is sensitive to the number of walls of the CNTs. For single-wall carbon nanotubes (SWCNTs), the G band is composed of two distinct contributions G+ and G-, while the G band for double-wall nanotubes is composed of one band with two main contributions from the inner and the outer tube. The G2D band can be fitted with one Lorentzian for single-wall tubes, while two distinct contributions are observed for double-wall carbon nanotubes (DWCNTs). Considerable variations of the G2D band are found with similar first order Raman spectra. Annealing influences the D- and RBM-band intensities. Electron irradiation has the effect of decreasing the G- and D-band wavenumbers but does not enhance the D-band intensity considerably. The down-shifts of the G- and D-band wavenumbers are correlated and are the same for two excitation wavelengths. This is consistent with the scattering of phonons around the K-point.

Mots clés: Raman; nanotubes; double wall; defects

Domaines: Matériaux

Pascal Puech, Emmanuel Flahaut, Ayman Bassil, Thomas Juffmann, François Beuneu, et al.. Raman bands of double-wall carbon nanotubes: comparison with single- and triple-wall carbon nanotubes, and influence of annealing and electron irradiation. Journal of Raman Spectroscopy, 2007, 38 (6), pp.714-720. ⟨10.1002/jrs.1690⟩. ⟨hal-03592265⟩