Recent advances in electrochemical meso- and β-functionalization of porphyrins and electrografting of diazonium porphyrins

Abdou K.D. Dimé , Asmae Bousfiha , Charles H. Devillers (1)

1 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

Recent studies on electrochemical meso and β-functionalization of porphyrins and electrografting of diazonium-porphyrin are presented. First the electrochemical oxidative CC coupling between porphyrins will be presented followed by the inter-and intramolecular meso and β-substitutions of porphyrins. Then the latest results on diazonium-porphyrin electrografting will be reviewed.

Mots clés: Organic electrosynthesis; Porphyrin; Anodic nucleophilic substitution; Electropolymerization; Diazonium-porphyrin electrografting

Domaines: Chimie de coordination; Chimie analytique; Chimie organique; Matériaux

Abdou K.D. Dimé, Asmae Bousfiha, Charles H. Devillers. Recent advances in electrochemical meso- and β-functionalization of porphyrins and electrografting of diazonium porphyrins. Current Opinion in Electrochemistry, 2020, 24, pp.69-78. ⟨10.1016/j.coelec.2020.07.004⟩. ⟨hal-03419604⟩