Chalcogen Bonding in Co-Crystals: Activation through 1,4-Perfluorophenylene vs. 4,4 '-Perfluorobiphenylene Cores
Résumé
The ability of alkylseleno/alkyltelluroacetylenes such as bis(selenomethylethynyl)-perfluorobenzene (4F-Se) to act as a ditopic chalcogen bond (ChB) donor in co-crystals with ditopic Lewis bases such as 4,4 '-bipyridine is extended here to the octafluorobiphenylene analog, 4,4 '-bis(selenomethylethynyl)-perfluorobiphenyl (8F-Se), with the more electron-rich 4,4 '-bipyridylethane (bpe), showing in the 1:1 (8F-Se)center dot(bpe) co-crystal a shorter and more linear C-Se center dot center dot center dot N ChB interaction than in (4F-Se)center dot(bpe), with Se center dot center dot center dot N distances down to 2.958(2) angstrom at 150 K, i.e., a reduction ratio of 0.85 vs. the van der Waals contact distance.
Domaines
Chimie
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