Different Approaches to Mid-Valent, Paramagnetic Half-Sandwich Complexes of the Heavier Group 6 Metals

Rinaldo Poli (1)

1 LSEO - Laboratoire de Synthèse et Electrosynthèse Organométalliques

The synthesis of deceptively simple carbonyl-free, mid-valent half-sandwich Mo and W compounds containing mainly phosphine, halide, and hydride ligands actually involves a number of complications requiring several tricks or synthetic detours to be overcome. The stability of some of the target systems also necessitates particular synthetic conditions.

Mots clés: Molybdenum; Tungsten; Cyclopentadienyl complexes; Phosphine complexes; Paramagnetic complexes

Domaines: Chimie de coordination

Rinaldo Poli. Different Approaches to Mid-Valent, Paramagnetic Half-Sandwich Complexes of the Heavier Group 6 Metals. SYNLETT, 1999, 1999 (7), pp.1019-1028. ⟨10.1055/s-1999-2746⟩. ⟨hal-03309810⟩