Chiral Tridentate-Based Ligands

Uchchhal Bandyopadhyay (1) , Basker Sundararaju (2) , Rinaldo Poli (1) , Eric Manoury (1)

1 LCC - Laboratoire de chimie de coordination
2 IIT Kanpur - Indian Institute of Technology Kanpur

The most recent tridentate ligands of any coordination pattern, which have been used in any reactions of asymmetric catalysis and which showed the greatest efficiencies in term of catalytic activities and selectivities, in particular enantioselectivities, are presented in this chapter. These include N,N,N ligands, such as Pybim, imininopyridine-oxazolines (IPO) , Bopa or Boxmi ligands; P,N,N ligands, like SpiroPAP and its analogs; N,P,N ligands, such as phosphine-bisoxazolines; P,N,P ligands, like imine-diphosphines; P,N,S ligands such as SpiroSAP; N,N,O ligands like pseudodipeptides or BinThro ligands; O,N,O ligands, such as imine-diols; N,C,N ligands, like Phebox or Phebim ligands; and many others.

Domaines: Chimie de coordination

Uchchhal Bandyopadhyay, Basker Sundararaju, Rinaldo Poli, Eric Manoury. Chiral Tridentate-Based Ligands. Montserrat Diéguez. Chiral Ligands, 1, CRC Press, pp.167-194, 2021, 978-0-367-4-28488. ⟨10.1201/9780367855734-5⟩. ⟨hal-03230854⟩