Correlating the Photophysical Properties with the Cure Index of Epoxy Nanocomposite Coatings
Résumé
Transparency is a crucial factor in developing functional and decorative thin films and coatings, but incorporation of nanoparticles into organic resins for improving their properties quite often makes them opaque. In this work, photophysical properties of epoxy/layered double hydroxide (LDH) nanocomposite coatings were correlated with the dispersion state of LDH in the epoxy resin. The quality of solid epoxy network was assessed in terms of the Cure Index (CI) in relation to the transparency of the films containing 0.1, 0.5, 0.7, 1.0, and 3.0 wt% Mg–Al–LDH and Zn–Al–LDHs. At high loadings, direct transmittance (YDirect) decreased, while the light scattering in the coatings improved with respect to the neat epoxy. The highest Zn–Al–LDH loading (3.0 wt%) slightly deteriorated the transparency (YDirect = 93.3), but it was still higher than that of epoxy nanocomposite containing 0.5 wt% Mg–Al–LDH (YDirect = 89.8). A Good label was assigned to the epoxy nanocomposites containing up to 1.0 wt% Zn–Al–LDH, while epoxy/Mg–Al–LDH nanocomposites were Poor in terms of the CI labeling when Mg–Al–LDH content was more than 0.1 wt%. An increase of about 28 °C in the Tg value after the addition of 0.1 wt% Zn–Al–LDH indicated that Zn–Al–LDH can make strong the interaction between the epoxy matrix and nanoplatelets. However, decrease in the Tg of the epoxy/Mg–Al–LDH nanocomposites was a signature of the weak interactions between the Mg–Al–LDH nanoplatelets and epoxy matrix due to inappropriate dispersion. In general, it was revealed for the first time that the CI enables correlating the chemical crosslinking with the photophysical properties of the epoxy/LDH nanocomposites.