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Synthesis of a Multichromophoric Array by Sequential CuAAC Reactions

Abstract : An easily synthesized α-hydroxy-β-azidotetrazole scaffold was used to build a three dimensional polychromic system. Different chromophores (coumarin, BODIPY and distyryl BODIPY) were incorporated into the structure by using sequential CuAAC reactions to form a series of dyads and a triad. A computational study of the resulting arrays showed that the predominant conformations brought the substituents into close spatial proximity. The triad exhibited FRET behaviour with notably efficient energy transfer values.
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https://hal.archives-ouvertes.fr/hal-03046880
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Submitted on : Tuesday, December 8, 2020 - 3:58:00 PM
Last modification on : Wednesday, November 3, 2021 - 6:03:45 AM
Long-term archiving on: : Tuesday, March 9, 2021 - 7:45:24 PM

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Assia Tafrioucht, Jad Rabah, Krystyna Baczko, Hélène Fensterbank, Rachel Méallet-Renault, et al.. Synthesis of a Multichromophoric Array by Sequential CuAAC Reactions. Dyes and Pigments, Elsevier, 2020, pp.109031. ⟨10.1016/j.dyepig.2020.109031⟩. ⟨hal-03046880⟩

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