Record spintronic harvesting of thermal fluctuations using paramagnetic molecular centers

B Chowrira (1) , L Kandpal (1) , D Mertz (1) , C Kieber (1) , A Bahouka (2) , R Bernard (1) , L Joly (1) , E Monteblanco (3) , S Mohapatra (1) , E Sternitzky (1) , V da Costa (1) , M Hehn (3) , F Montaigne (3) , B Vileno (4) , F Choueikani (5) , P Ohresser (5) , D Lacour (3) , W Weber (1) , S Boukari (1) , M Bowen (1)

1 IPCMS - Institut de Physique et Chimie des Matériaux de Strasbourg
2 IREPA LASER - IREPA LASER
3 IJL - Institut Jean Lamour
4 Institut de Chimie de Strasbourg
5 SSOLEIL - Synchrotron SOLEIL

Experiments and theory are reexamining how the laws of thermodynamics are expressed in a quantum world. Most quantum thermodynamics research is performed at sub-Kelvin temperatures to prevent thermal fluctuations from smearing the quantum engine's discrete energy levels that mediate the asymmetric shuffling of electrons between the electrodes. Meanwhile, several groups report that building an electron-spin based implementation by placing the discrete spin states of paramagnetic centers between ferromagnetic electrodes can not only overcome this drawback, but also induce a net electrical power output despite an apparent thermal equilibrium. We illustrate this thermodynamics conundrum through measurements on several devices of large output power, which endures beyond room temperature. We've inserted the Co paramagnetic center in Co phthalocyanine molecules between electron spin-selecting Fe/C60 interfaces within vertical molecular nanojunctions. We observe output power as high as 450nW(24nW) at 40K(360K), which leapfrogs previous results, as well as classical spintronic energy harvesting strategies involving a thermal gradient. Our data links magnetic correlations between the fluctuating paramagnetic centers and output power. This device class also behaves as a spintronically controlled switch of current flow, and of its direction. We discuss the conceptual challenges raised by these measurements. Better understanding the phenomenon and further developing this technology could help accelerate the transition to clean energy. Abstract (150 words) Several experiments have suggested that building a quantum engine using the electron spin enables the harvesting of thermal fluctuations on paramagnetic centers even though the device is at thermal equilibrium. We illustrate this thermodynamics conundrum through measurements on several devices of large output power, which endures beyond room temperature. We've inserted the Co paramagnetic center in Co phthalocyanine molecules between electron spin-selecting Fe/C60 interfaces within vertical molecular nanojunctions. We observe output power as high as 450nW(24nW) at 40K(360K), which leapfrogs previous results, as well as classical spintronic energy harvesting strategies involving a thermal gradient. Our data links magnetic correlations between the fluctuating paramagnetic centers and output power. This device class also behaves as a spintronically controlled switch of current flow, and of its direction. We discuss the

Domaines: Physique [physics]; Matière Condensée [cond-mat]

B Chowrira, L Kandpal, D Mertz, C Kieber, A Bahouka, et al.. Record spintronic harvesting of thermal fluctuations using paramagnetic molecular centers. 2020. ⟨hal-03001215⟩