DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

Michael Bruce , Aurora Castro , Paul Humphrey , Peter Maitlis , Natasha Zaitseva , Lydie Viau (1) , Mark Humphrey

1 UTINAM - Univers, Transport, Interfaces, Nanostructures, Atmosphère et environnement, Molécules (UMR 6213)

For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2‐ from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2‐) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2‐).

Mots clés: calcium di(carbido)tetracosa(carbonyl) decaruthenium(2‐); di(Carbido)tetracosa(Carbonyl) decaruthenium(2‐) salts; ruthenium

Domaines: Chimie

Michael Bruce, Aurora Castro, Paul Humphrey, Peter Maitlis, Natasha Zaitseva, et al.. DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts. Gregory S. Girolami Alfred P. Sattelberger. Inorganic Syntheses, 36, Wiley, pp.124-126, 2014, Inorganic Syntheses, 9781118744994. ⟨10.1002/9781118744994.ch23⟩. ⟨hal-02998778⟩