Photocatalyzed Amidoarylation of 1,3‐Butadiene

Cyrille Gosset (1) , Aurélien Moncomble (2) , Clément Dumont (1) , Sylvain Pellegrini (1) , Till Bousquet (1) , Mathieu Sauthier (1) , Lydie Pelinski (1)

1 UCCS - Unité de Catalyse et Chimie du Solide - UMR 8181
2 LASIRE - Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516

1,3-Butadiene is involved in a photocatalyzed amidoarylation reaction that allows the synthesis of N-allyl amides. The reaction was evaluated on a wide range of aryl diazonium salts and nitriles as co-reactants. Selectivity issues were studied from the help of a computational approach.

Mots clés: Visible-light-promoted photocatalysis; 1; 3butadiene; Diazonium salts

Domaines: Chimie organique; Catalyse

Cyrille Gosset, Aurélien Moncomble, Clément Dumont, Sylvain Pellegrini, Till Bousquet, et al.. Photocatalyzed Amidoarylation of 1,3‐Butadiene. Advanced Synthesis and Catalysis, 2020, 362 (15), pp.3100-3104. ⟨10.1002/adsc.202000071⟩. ⟨hal-02963037⟩