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C60 end-capped polystyrene stars

Abstract : A hexaarm hexachloropolystyrene star polymer 1 ([M with combining macron]n= 18 000 g mol–1) is functionalized by reaction with Me3SiN3 to give the hexaazido star polymer 2; reduction of 2 by PPh3/H2O leads to the hexaamine star polymer 3, and reaction of 2 with a two-fold excess of C60 gives the hexafullerence star polymer 4, characterized by size-exclusion chromatography, NMR, thermal-gravimetry analysis and CV.
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https://hal.archives-ouvertes.fr/hal-02930414
Contributor : Eric Cloutet Connect in order to contact the contributor
Submitted on : Friday, September 4, 2020 - 1:55:51 PM
Last modification on : Wednesday, April 7, 2021 - 3:18:13 PM

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Eric Cloutet, Yves Gnanou, Jean-Luc Fillaut, Didier Astruc. C60 end-capped polystyrene stars. Chemical Communications, Royal Society of Chemistry, 1996, pp.1565. ⟨10.1039/CC9960001565⟩. ⟨hal-02930414⟩

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