Liquid–Liquid Equilibria of Binary and Ternary Systems Methanol/Water + n -Hexane, + n -Octane, + n -Dodecane, and + n -Hexadecane in the Temperature Range between T = 283.15 K and T = 333.15 K

Cécile Lindemann (1) , Pierre Duchet-Suchaux (2) , Antonio Razzouk (3) , Ilham Mokbel (1, 4) , Jacques Jose (1)

1 LMI - Laboratoire des Multimatériaux et Interfaces
2 TOTAL S.A.
3 Département de Chimie et de Biochimie (Faculté des Sciences II, Université Jdeideth El Matn)
4 UJM - Université Jean Monnet - Saint-Étienne

Original very low solubility data for binary (methanol + dodecane) and ternary systems (methanol/water + hexane, or octane, or dodecane, or hexadecane) under atmospheric pressure at three temperatures between 283.15 and 333.15 K are reported. The experimental values were compared with literature data when available. Two models (NRTL and UNIQUAC) were used to correlate and predict the experimental data.

Mots clés: Hydrocarbons; Alcohols; Solubility; Water; UNIQUAC model

Domaines: Chimie; Chimie organique; Matériaux

Cécile Lindemann, Pierre Duchet-Suchaux, Antonio Razzouk, Ilham Mokbel, Jacques Jose. Liquid–Liquid Equilibria of Binary and Ternary Systems Methanol/Water + n -Hexane, + n -Octane, + n -Dodecane, and + n -Hexadecane in the Temperature Range between T = 283.15 K and T = 333.15 K. Journal of Chemical and Engineering Data, 2016, 61 (7), pp.2412-2418. ⟨10.1021/acs.jced.6b00022⟩. ⟨hal-02881406⟩