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On the spectroscopy of Bi3+ in d10 post-transition metal oxides

Abstract : The optical spectroscopy of Bi3+ in d10-based post transition metal oxides (i. e. gallates, germanates, antimonates indates, stannates) is reviewed and analyzed in the frame of empirical models. 20 different compounds are examined. From this, a methodology is introduced to identify the preferred doping sites for Bi3+ and predict the intra- or extra-ionic origin of the Bi3+ emission in these systems. Further, the emission process in calcite-structured InBO3:Bi and GaBO3:Bi is reconsidered.
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https://hal.archives-ouvertes.fr/hal-02536933
Contributor : Stéphanie Bonnefoy <>
Submitted on : Wednesday, April 8, 2020 - 2:40:13 PM
Last modification on : Thursday, April 9, 2020 - 1:42:54 AM

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Philippe Boutinaud. On the spectroscopy of Bi3+ in d10 post-transition metal oxides. Journal of Luminescence, Elsevier, 2020, 223, pp.117219. ⟨10.1016/j.jlumin.2020.117219⟩. ⟨hal-02536933⟩

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