Closing the loop: Life cycle assessment and optimization of a PEMFC platinum-based catalyst recycling process

Lucien Duclos; Raphaël Chattot; Laetitia Dubau; Pierre-Xavier Thivel; Guillaume Mandil; Valérie Laforest; Marco Bolloli; Rémi Vincent; Lenka Svecova

doi:10.1039/C9GC03630J

Journal articles

Closing the loop: Life cycle assessment and optimization of a PEMFC platinum-based catalyst recycling process

Lucien Duclos ¹ Raphaël Chattot ¹ Laetitia Dubau ¹ Pierre-Xavier Thivel ¹ Guillaume Mandil ² Valérie Laforest ^{3, 4, 5} Marco Bolloli ⁶ Rémi Vincent ⁶ Lenka Svecova ¹

1 EIP - Electrochimie Interfaciale et Procédés

LEPMI - Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces

2 G-SCOP_CPP - Conception Produit Process

G-SCOP - Laboratoire des sciences pour la conception, l'optimisation et la production

3 FAYOL-ENSMSE - Institut Henri Fayol

4 Mines Saint-Étienne MSE - École des Mines de Saint-Étienne

5 EVS - Environnement Ville Société

6 LITEN - Laboratoire d'Innovation pour les Technologies des Energies Nouvelles et les nanomatériaux

Abstract : This study is focused on the development of environmentally friendly recycling method for selective recovery in a closed loop manner of Co and Pt from Pt3Co/C catalyst used as the PEMFC cathode. Pt and Co selective separation was carried out using two different hydrometallurgical alternatives based either on ion exchange resin or solvent extraction. The recycling process was optimized in order to maximize the platinum recovery yield, which reached 83% and 77% of the Pt initially present in the MEA using respectively solvent extraction or ion exchange resin separation alternatives. The recovered platinum alkaline solutions have been further used for Pt/C particles synthesis via a modified polyol method and it was shown that although the resin alternative resulted in slightly lower recovery yield, the catalyst prepared via this alternative satisfied morphological and electrochemical properties for the oxygen reduction reaction (ORR) by performing similarly to a commercial state-of-art Pt/C catalyst. The feasibility of closed loop Pt/C catalyst recycling was thus proven. The environmental impacts of the two recycling alternatives have been compared using life cycle assessment methodology (LCA) and similar impacts have been found for both alternatives from the point of view of the entire MEA life cycle. The ion exchange resin alternative has thus been selected as the most appropriate one.

Document type :

Journal articles

Domain :

Chemical Sciences

Chemical Sciences / Inorganic chemistry

Environmental Sciences

Environmental Sciences / Environmental and Society

Environmental Sciences / Environmental Engineering

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https://hal.archives-ouvertes.fr/hal-02473412
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Submitted on : Monday, February 10, 2020 - 4:56:34 PM
Last modification on : Wednesday, January 26, 2022 - 3:14:50 AM

Closing the loop: Life cycle assessment and optimization of a PEMFC platinum-based catalyst recycling process

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Closing the loop: Life cycle assessment and optimization of a PEMFC platinum-based catalyst recycling process

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