Coordination complexes involving sydnones as ligands

Xavier Bantreil (1) , Nicolas Pétry (1) , Frédéric Lamaty (1)

1 IBMM - Institut des Biomolécules Max Mousseron [Pôle Chimie Balard]

Sydnones are mesioionic compounds studied for years for their versatile reactivity in substitution reactions, sydnone-alkyne or sydnone-alkene cycloaddition reactions. This perspective article focuses on the use of sydnones in coordination complexes, either through a metalation on one of the carbons of the sydnone ring, its modification to obtain polydentate ligands, or its use as a polar moiety that could influence the properties of the final complex. Such compounds are valuable either from a synthetic point of view or for their biological properties.

Mots clés: Mechanochemistry; Ball mills; Sydnone; Heterocycle; X- ray diffractions; Review of literature

Domaines: Chimie

Xavier Bantreil, Nicolas Pétry, Frédéric Lamaty. Coordination complexes involving sydnones as ligands. Dalton Transactions, 2019, 48 (42), pp.15753-15761. ⟨10.1039/c9dt03115d⟩. ⟨hal-02370898⟩