Insights into B-Mg-Metasomatism at the Ranger U Deposit (NT, Australia) and Comparison with Canadian Unconformity-Related U Deposits

Joséphine Gigon (1) , Roger G Skirrow (2) , Matthieu Harlaux (3) , Antonin Richard (1) , Julien Mercadier (1) , Irvine R Annesley (1) , Johan Villeneuve (4)

1 GeoRessources
2 Geoscience Australia, Canberra, ACT
3 Department of Earth Sciences [Geneva]
4 CRPG - Centre de Recherches Pétrographiques et Géochimiques

The Ranger deposit (Northern Territory, Australia) is one of the largest uranium deposits in the world. Uranium mineralisation occurs in crystalline basement rocks and is thought to belong to the unconformity-related category. In order to address the sources of magnesium and boron, and the temperature of the fluids related to boron and magnesium metasomatism that occurred shortly before and during the main uranium stage, in situ analyses of chlorite and tourmaline were carried out. The chemical composition of tourmaline shows an elevated X-site vacancy and a low Fe tot /(Fe tot + Mg) ratio typical of Mg-foitite. Uranium-related chlorite has relatively low Fe content (0.28-0.83 apfu) and high Mg content (3.08-3.84 apfu), with Si/Al = 1.08−1.22 and Mg/(Mg + Fe tot) = 0.80−0.93 indicating a composition lying between the clinochlore and Mg-amesite fields. Chlorite composition indicates crystallisation temperature of 101-163 • C. The boron isotopic composition of tourmaline shows a range of δ 11 B values of~1-9%. A model is proposed involving two boron sources that contribute to a mixed isotopic signature: (i) evaporated seawater, which is typically enriched in magnesium and boron (δ 11 B~40%), and (ii) boron from the crystalline basement (δ 11 B~−30 to +10%), which appears to be the dominant source. Collectively, the data indicate similar tourmaline chemistry but significant differences of tourmaline boron isotopic composition and chlorite chemistry between the Ranger deposit and some of the Canadian unconformity-related uranium deposits. However, lithogeochemical exploration approaches based on identification of boron-and magnesium-enriched zones may be usefully applied to uranium exploration in the Northern Territory.

Mots clés: tourmaline; chlorite; boron isotopes; metasomatism; unconformity-related uranium deposits; Ranger

Domaines: Géologie appliquée

Joséphine Gigon, Roger G Skirrow, Matthieu Harlaux, Antonin Richard, Julien Mercadier, et al.. Insights into B-Mg-Metasomatism at the Ranger U Deposit (NT, Australia) and Comparison with Canadian Unconformity-Related U Deposits. Minerals, 2019, 9 (7), pp.432. ⟨10.3390/min9070432⟩. ⟨hal-02334093⟩