Determining Enantiomeric Purity by NMR: Deuterium 2D NMR at Natural Abundance in Weakly Oriented Chiral Liquid Crystals

Philippe Lesot (1, 2) , Muriel Sarfati (1) , Denis Merlet (1) , Jacques Courtieu (1) , Bernard Ancian (3) , Claude Brevard (4)

1 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay
2 CNRS - Centre National de la Recherche Scientifique
3 UPMC - Université Pierre et Marie Curie - Paris 6 - UFR de Médecine Pierre et Marie Curie
4 Bruker

The spectral enantiodiscriminations using natural abundance deuterium (NAD) 2D-NMR in polypeptide chiral liquid crystals is discussed.

Mots clés: NAD; Deuterium; Enantiodiscrimination; 2D NMR; Chirality; PBLG

Domaines: Chimie analytique

Philippe Lesot, Muriel Sarfati, Denis Merlet, Jacques Courtieu, Bernard Ancian, et al.. Determining Enantiomeric Purity by NMR: Deuterium 2D NMR at Natural Abundance in Weakly Oriented Chiral Liquid Crystals. Bruker Report, 2001, 149, pp.29-33. ⟨hal-02321012⟩