Thermal Oxidation of Carbonaceous Nanomaterials Revisited: Evidence of Mechanism Changes

Emmanuel Picheau (1) , Ferdinand Hof (1) , Alain Derré (1) , Barbara Daffos (2, 3) , Alain Pénicaud (1)

1 CRPP - Centre de Recherche Paul Pascal
2 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux
3 RS2E - Réseau sur le stockage électrochimique de l'énergie

Kinetic data, for example, activation energy and reaction order, are crucial for the understanding of chemical reactions and processes. Here, we describe a novel method for obtaining kinetic data based on thermogravimetric measurements (TGA) that exploits in each measurement multiple successive isothermal steps (SIS). We applied this method to the notoriously challenging carbon combustion process for vastly different carbons for oxygen molar fractions between 1.4 % and 90 %. Our obtained apparent EA values are within the wide range of results in the literature and vary in a systematic way with the oxygen partial pressure. The improved accuracy and large amount of obtainable data allowed us to show that the majority of experimentally obtained apparent data for apparent EA are neither in a kinetic regime nor in a diffusion‐controlled one but rather in a transition regime.

Mots clés: Carbon black; Carbon nanotubes; Graphite; Kinetics; Thermal oxidation

Domaines: Matériaux

Emmanuel Picheau, Ferdinand Hof, Alain Derré, Barbara Daffos, Alain Pénicaud. Thermal Oxidation of Carbonaceous Nanomaterials Revisited: Evidence of Mechanism Changes. Angewandte Chemie International Edition, 2019, ⟨10.1002/anie.201906026⟩. ⟨hal-02309164⟩