Photoionization microscopy: Hydrogenic theory in semiparabolic coordinates and comparison with experimental results

P. Kalaitzis (1) , S. Danakas (1) , F. Lepine (2) , C. Bordas (2) , S. Cohen (1)

1 University of Ioannina
2 ILM - Institut Lumière Matière [Villeurbanne]

Photoionization microscopy (PM) is an experimental method allowing for high-resolution measurements of the electron current probability density in the case of photoionization of an atom in an external uniform static electric field. PM is based on high-resolution velocity-map imaging and offers the unique opportunity to observe the quantum oscillatory spatial structure of the outgoing electron flux. We present the basic elements of the quantum-mechanical theoretical framework of PM for hydrogenic systems near threshold. Our development is based on the computationally more convenient semiparabolic coordinate system. Theoretical results are first subjected to a quantitative comparison with hydrogenic images corresponding to quasibound states and a qualitative comparison with nonresonant images of multielectron atoms. Subsequently, particular attention is paid on the structure of the electron's momentum distribution transversely to the static field (i.e., of the angularly integrated differential cross-section as a function of electron energy and radius of impact on the detector). Such 2D maps provide at a glance a complete picture of the peculiarities of the differential cross-section over the entire near-threshold energy range. Hydrogenic transverse momentum distributions are computed for the cases of the ground and excited initial states and single- and two-photon ionization schemes. Their characteristics of general nature are identified by comparing the hydrogenic distributions among themselves, as well as with a presently recorded experimental distribution concerning the magnesium atom. Finally, specificities attributed to different target atoms, initial states, and excitation scenarios are also discussed, along with directions of further work.

Mots clés: Atomic & molecular processes in external fields; Electronic excitation & ionization; Single- and few-photon ionization & excitation; Stark effect

Domaines: Chimie; Physique [physics]; Sciences de l'ingénieur [physics]

P. Kalaitzis, S. Danakas, F. Lepine, C. Bordas, S. Cohen. Photoionization microscopy: Hydrogenic theory in semiparabolic coordinates and comparison with experimental results. Physical Review A, 2018, 97 (5), pp.053412. ⟨10.1103/PhysRevA.97.053412⟩. ⟨hal-02285750⟩