Mixed Metallic Ba(Co,Fe)X 0.2 O 3−δ (X = F, Cl) Hexagonal Perovskites: Drastic Effect of Fe-Incorporation on Structural and Electronic Features
Résumé
Starting from the parent 10H–Ba5Co5X1–xO13−δ (trimeric strings of face-sharing CoO6 octahedra with terminal CoO4 tetrahedra, stacking sequence (chhch′)2) and 6H–Ba6Co6X1–xO16-δ (similar with tetrameric strings, stacking sequence chhhch′) hexagonal perovskites forms (X = F, Cl; c, h = [BaO3] layers ; h′ = [BaOX1–y] layers), we show here that the Fe incorporation leads to large domains of solid solutions for both X = F and Cl but exclusively stabilizes the 10H-form independently of the synthesis method. In this form, the lowest concentration of h-layers is stabilized by a sensitive metal reduction with increasing the Fe ratio. In a more general context of competition between several hexagonal perovskite polymorphs available for most of the transition metals, this redox change is most probably the key factor driving 1D (face-sharing chains) to 3D (corner-sharing) connectivities. Strikingly, ND data evidence the location of oxygen deficiencies in the tetrahedral (Co/Fe) coordination. This effect is exaggerated at high temperature, while (Co/Fe)O4-δ coordinations are completed by the displacement of X– anions toward the (Co/Fe) sphere of coordination following a “push-and-pull” mechanism within h′–[BaOX1–y] layers. The Fe-incorporation is also accompanied by increasing conduction gaps with predominant 1D variable range hopping. The full series show antiferromagnetic behavior with increasing TN as [Fe] increases. For Fe-rich compounds TN is estimated about 600 K, as rarely observed for hexagonal perovskite compounds. Finally, magnetic structures of all iron-doped compounds show a site-to-site AFM ordering, different of the magnetic structure of Co-only parent compounds. Here, DFT calculations predict low-spin octahedral Co configurations, but high-spin Fe species in the same sites.