Redox Activity of Sodium Vanadium Oxides towards Oxidation in Na Ion Batteries

Evan Adamczyk (1) , Muthaiyan Gnanavel (1) , Valérie Pralong (1)

1 CRISMAT - Laboratoire de cristallographie et sciences des matériaux

The search for new materials that could be used as electrode material for Na-ion batteries is one of the most challenging issues of today. Many transition metal oxide families as well as transition metal polyanionic frameworks have been proposed over the last five years. In this work, we report the sodium extraction from Na2V3O7, which is a tunnel type structure built of [V3O7]2−∞ nanotubes held by sodium ions. We report a reversible charge capacity of 80 mAh/g at 2.8 V vs. Na+/Na due to the V5+/V4+ redox activity. No oxygen redox activity has been observed for this material nor for the vanadium (5+) oxide Na4V2O7.

Mots clés: Na2V3O7; Sodium vanadate; Na-ion batteries; Na4V2O7

Domaines: Chimie; Matériaux

Evan Adamczyk, Muthaiyan Gnanavel, Valérie Pralong. Redox Activity of Sodium Vanadium Oxides towards Oxidation in Na Ion Batteries. Materials, 2018, 11 (6), pp.1021. ⟨10.3390/ma11061021⟩. ⟨hal-02163149⟩