Iron-Catalyzed Minisci Type Acetylation of N-Heteroarenes Mediated by CH(OEt)3/TBHP

A Srinivasulu , B Shantharjun , D Vani , Chinna Ashalu , Aabid Mohd (1) , Joanna Wencel-Delord (1) , Francoise Colobert-Leuenberger (1) , R Reddy

1 LIMA - Laboratoire d'innovation moléculaire et applications

Iron-catalyzed acetylation of electron deficient N-heteroarenes has been reported using triethylorthoformate as robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole.

Mots clés: SYNCAT; SYNCAT

Domaines: Chimie organique

A Srinivasulu, B Shantharjun, D Vani, Chinna Ashalu, Aabid Mohd, et al.. Iron-Catalyzed Minisci Type Acetylation of N-Heteroarenes Mediated by CH(OEt)3/TBHP. European Journal of Organic Chemistry, 2019, 2019 (8), pp.1815-1819. ⟨10.1002/ejoc.201900033⟩. ⟨hal-02161629⟩