Synthetic Approaches to C-Glucosinolates

Vincent Aucagne (1) , David Gueyrard , Arnaud Tatibouët (1) , Alain Quinsac , Patrick Rollin (1)

1 ICOA - Institut de Chimie Organique et Analytique

In these pages, short and efficient synthetic approaches to C-analogs of glucosinolates are described. Starting from d-glucose, C-glucotropaeolin (6) and C-glucocapparin (11) were synthesized in three steps. Preliminary enzymatic assays involving sulfatase and myrosinase have been performed.

Domaines: Sciences du Vivant [q-bio]

Vincent Aucagne, David Gueyrard, Arnaud Tatibouët, Alain Quinsac, Patrick Rollin. Synthetic Approaches to C-Glucosinolates. Tetrahedron, 2000, 56 (17), pp.2647-2654. ⟨10.1016/S0040-4020(00)00153-8⟩. ⟨hal-02086037⟩