# Structural Relaxation Dynamics and Annealing Effects of Sodium Silicate Glass

Abstract : Here we report high--precision measurements of structural relaxation dynamics in the glass transition range at the intermediate and short length scale for a strong sodium silicate glass during long annealing times. We evidence for the first time the heterogeneous dynamics at the intermediate range order by probing the acoustic longitudinal frequency in the GHz region by Brillouin light scattering spectroscopy. Or, from \textit{in--situ} Raman measurements we show that relaxation is indeed homogenous at the interatomic length scale. Our results show that the dynamics at the intermediate range order contains two distinct relaxation time scales, a fast and a slow component, differing by about a tenfold factor below $T_{g}$ and approaching to one another past the glass transition. The slow relaxation time agrees with the shear relaxation time, proving that Si--O bond breaking constitutes the primary control of structural relaxation at the intermediate range order.
Document type :
Journal articles
Domain :

https://hal.archives-ouvertes.fr/hal-02070892
Contributor : Laëtitia Legoupil <>
Submitted on : Monday, March 18, 2019 - 12:02:55 PM
Last modification on : Tuesday, March 19, 2019 - 1:27:52 AM

### Citation

Mohamed Naji, Francesco Piazza, Guillaume Guimbretiere, Aurélien Canizares, Yann Vaills. Structural Relaxation Dynamics and Annealing Effects of Sodium Silicate Glass. Journal of Physical Chemistry B, American Chemical Society, 2013, 117 (18), pp.5757-5764. ⟨10.1021/jp401112s⟩. ⟨hal-02070892⟩

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