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The oxidation of hydrogen cyanide and related chemistry

P. Dagaut 1 P Glarborg 2 M Alzueta 3
1 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement
2 DTU - Technical University of Denmark [Lyngby]
3 Universidad de Zaragossa
Abstract : For modeling the formation of nitrogen oxides in combustion via both the prompt-NO and the fuel-NO mechanisms, as well as for modeling the reduction of nitrogen oxides via reburning, a good knowledge of the kinetics of oxidation of hydrogen cyanide (HCN) is required. The formation routes to HCN and the thermochemistry of HCN-related species are reviewed. The available kinetic data for the oxidation of HCN are presented and a comprehensive detailed chemical kinetic reaction mechanism for the oxidation of HCN is proposed and discussed.
Keywords : hydrogen cyanide HCN nitrogen oxides fuel-NO Kinetic modeling oxidation -mechanism flow reactor flame structure jet-stirred reactor
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https://hal.archives-ouvertes.fr/hal-02020654
Contributor : Philippe Dagaut Connect in order to contact the contributor
Submitted on : Friday, February 15, 2019 - 1:09:39 PM
Last modification on : Tuesday, October 12, 2021 - 5:20:47 PM

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CNRS | UNIV-ORLEANS | CNRS_ICARE

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P. Dagaut, P Glarborg, M Alzueta. The oxidation of hydrogen cyanide and related chemistry. Progress in Energy and Combustion Science, Elsevier, 2008, 34 (1), pp.1-46. ⟨10.1016/j.pecs.2007.02.004⟩. ⟨hal-02020654⟩

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