Chiral symmetry breaking yields the I-Au60 perfect golden shell of singular rigidity

S.-M. Mullins , H.-Ch. Weissker (1) , R. Sinha-Roy (1) , J. Pelayo , I. Garzón , R. Whetten , X. López-Lozano (2)

1 CINaM - Centre Interdisciplinaire de Nanoscience de Marseille
2 UTSA - The University of Texas at San Antonio

The combination of profound chirality and high symmetry on the nm-scale is unusual and would open exciting avenues, both fundamental and applied. Here we show how the unique electronic structure and bonding of quasi-2D gold makes this possible. We report a chiral symmetry breaking, i.e., the spontaneous formation of a chiral-icosahedral shell (I−Au 60) from achiral (I h) precursor forms, accompanied by a contraction in the Au-Au bonding and hence the radius of this perfect golden sphere, in which all 60 sites are chemically equivalent. This structure, which resembles the most complex of semi-regular (Archimedean) polyhedra (3 4 .5 *), may be viewed as an optimal solution to the topological problem: how to close a 60-vertex 2D (triangular) net in 3D. The singular rigidity of the I−Au 60 manifests in uniquely discrete structural, vibrational, electronic, and optical signatures, which we report herein as a guide to its experimental detection and ultimately its isolation in material forms.

Domaines: Science des matériaux [cond-mat.mtrl-sci]

S.-M. Mullins, H.-Ch. Weissker, R. Sinha-Roy, J. Pelayo, I. Garzón, et al.. Chiral symmetry breaking yields the I-Au60 perfect golden shell of singular rigidity. Nature Communications, 2018, 9 (1), ⟨10.1038/s41467-018-05215-3⟩. ⟨hal-01958555⟩