(Terpyridine)(acetylacetonate)ruthenium(II) complex with a zwitterionic form of phosphoniophenylcyanamide ligand

Lucinda Dudd (1) , Matthew Hart (1) , David Ring (1) , Elodie Sondaz (1) , Jacques Bonvoisin (1) , Yannick Coppel (2)

1 CEMES - Centre d'élaboration de matériaux et d'études structurales
2 LCC - Laboratoire de chimie de coordination

The complex [Ru(tpy)(acac)(PPh4cyd)][PF6] (where tpy: 2,20:60,200-terpyridine, acac: acetylacetone and PPh4cyd: 4-triphenylphosphoniophenylcyanamide) has been synthesized. It contains the zwitterionic form of the phosphoniophenylcyanamide ligand. Characterizations were carried out using IR, ES-MS, UV–Vis, electrochemistry and 1H, 13C and 31P NMR spectroscopy.

Mots clés: Ruthenium(II) complex; cyanamide; NMR; Zwitterion; Phosphonium

Domaines: Chimie de coordination

Lucinda Dudd, Matthew Hart, David Ring, Elodie Sondaz, Jacques Bonvoisin, et al.. (Terpyridine)(acetylacetonate)ruthenium(II) complex with a zwitterionic form of phosphoniophenylcyanamide ligand. Inorganic Chemistry Communications, 2003, 6 (11), pp.1400 - 1405. ⟨10.1016/J.inoche.2003.08.016⟩. ⟨hal-01738634⟩