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Exciton-phonon coupling in a CsPbBr 3 single nanocrystal

Abstract : We have performed micro-photoluminescence measurements on a single CsPbBr3 nanocrystal (NC) with a size comparable to the Bohr diameter (7 nm). When the NC has an orthorhombic crystal symmetry, we observe an exciton fine structure composed of three peaks linearly polarized. We took advantage of the polarization properties of micro-photoluminescence to monitor in situ both the energy and linewidth of individual peaks when increasing temperature. We reveal that two regimes exist, at low and high temperature, which are dominated by acoustic or longitudinal optical phonon (Fröhlich term) couplings, respectively. The acoustic contribution does not change when the energy of the excitonic transition varies in the range of 2.46–2.62 eV, i.e., with NC sizes corresponding to this range. We find that line broadening is mainly ruled by the Fröhlich term, which is consistent with the polar nature of CsPbBr3.
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Submitted on : Friday, March 30, 2018 - 3:45:20 PM
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Julien Ramade, Léon Marcel Andriambariarijaona, Violette Steinmetz, Nicolas Goubet, Laurent Legrand, et al.. Exciton-phonon coupling in a CsPbBr 3 single nanocrystal. Applied Physics Letters, American Institute of Physics, 2018, 112 (7), pp.072104. ⟨10.1063/1.5018413⟩. ⟨hal-01736974⟩

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