Isolation and structural characterization of a titanacyclopropane as key intermediate in the double aryl Grignard addition to 2-(arylethynyl)pyridine derivatives

Francesco Foschi (1) , Torsten Roth (1) , Markus Enders (1) , Hubert Wadepohl (1) , Eric Clot (2) , Lutz H. Gade (1)

1 Anorganisch-Chemisches Institut der Universität Heidelberg
2 ICGM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Domaines: Chimie-Physique [physics.chem-ph]; Catalyse; Chimie théorique et/ou physique; Chimie organique

Francesco Foschi, Torsten Roth, Markus Enders, Hubert Wadepohl, Eric Clot, et al.. Isolation and structural characterization of a titanacyclopropane as key intermediate in the double aryl Grignard addition to 2-(arylethynyl)pyridine derivatives. Chemical Communications, 2018, 54 (18), pp.2228 - 2231. ⟨10.1039/c8cc00478a⟩. ⟨hal-01718895⟩