Metallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks

Karim Aissou; Muhammad Mumtaz; Alberto Alvarez-Fernandez; Jean Mercat; Ségolène Antoine; Gilles Pécastaings; Virginie Ponsinet; Cécile Dobrzynski; Guillaume Fleury; Georges Hadziioannou

doi:10.1002/marc.201700754

Metallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks

Karim Aissou ^{1, 2, *} Muhammad Mumtaz ^{1, 2} Alberto Alvarez-Fernandez ^{1, 3, 2} Jean Mercat ¹ Ségolène Antoine ^{1, 2} Gilles Pécastaings ^{1, 2} Virginie Ponsinet ³ Cécile Dobrzynski ⁴ Guillaume Fleury ^{1, 2} Georges Hadziioannou ^{1, 2}

* Auteur correspondant

1 LCPO - Laboratoire de Chimie des Polymères Organiques

2 TEAM 4 LCPO

3 CRPP - Centre de Recherche Paul Pascal

4 CARDAMOM - Certified Adaptive discRete moDels for robust simulAtions of CoMplex flOws with Moving fronts

IMB - Institut de Mathématiques de Bordeaux, Inria Bordeaux - Sud-Ouest

Abstract : Nanotemplates derived from the self-assembly of AB-type block copolymers provide an elegant route to achieve well-defined metallic dot arrays, even if the variety of pattern symmetries is restricted due to the limited number of structures offered by microphase separated diblock copolymers. A strategy that relies on the use of complex network structures accessible through the self-assembly of linear ABC-type terpolymers is presented for the formation of metallic nanodots arrays with “outside-the-box” symmetries. Patterned templates formed by the cubic Q214 and orthorhombic O70 network structures are used as excellent platforms to build well-ordered gold nanodot arrays with unique p3m1 and p2 symmetries, respectively. A simple yet efficient blending strategy is used to tune the critical dimensions of the p3m1 pattern while laterally ordered gold nanodot arrays are also demonstrated through a directed self-assembly approach. Such highly ordered gold nanodots with tunable particle dimensions and array periods, enabling the control of their plasmonic responses, are attractive probes for biological imaging.

Keywords : Self-assembly Thin films Triblock terpolymers Gold nanodots Network structures

Type de document :

Article dans une revue

Macromolecular Rapid Communications, Wiley-VCH Verlag, 2018, 〈10.1002/marc.201700754〉

Domaine :

Chimie / Polymères

Liste complète des métadonnées

https://hal.archives-ouvertes.fr/hal-01688010
Contributeur : Eric Cloutet <>
Soumis le : vendredi 19 janvier 2018 - 09:11:38
Dernière modification le : mercredi 31 octobre 2018 - 01:07:52

Metallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks

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