-. Pelegri, E. M. Day, E. Lin, and H. D. Maynard, Therapeutic protein-polymer conjugates: advancing beyond PEGylation, Journal of the American Chemical Society, vol.15, issue.1, pp.14323-14332, 2014.

A. T. Dirks, R. J. Nolte, and J. J. Cornelissen, Protein-polymer hybrid amphiphiles, Advanced Materials, vol.20, pp.3953-3957, 2008.

K. Velonia, A. E. Rowan, and R. J. Nolte, Lipase polystyrene giant amphiphiles, Journal of the American Chemical Society, vol.124, pp.4224-4225, 2002.

M. J. Boerakker, J. M. Hannink, P. H. Bomans, P. M. Frederik, R. J. Nolte et al., Giant amphiphiles by cofactor reconstitution, Angewandte Chemie International Edition, vol.41, pp.4239-4241, 2002.

M. J. Boerakker, N. E. Botterhuis, P. H. Bomans, P. M. Frederik, E. M. Meijer et al., Aggregation behavior of giant amphiphiles prepared by cofactor reconstitution, Chemistry-A European Journal, vol.12, pp.6071-6080, 2006.

L. Droumaguet, B. Velonia, and K. , Situ ATRP-Mediated Hierarchical Formation of Giant Amphiphile Bionanoreactors, vol.120, pp.6359-6362, 2008.

L. Droumaguet, B. Mantovani, G. Haddleton, D. M. Velonia, and K. , Formation of giant amphiphiles by post-functionalization of hydrophilic protein-polymer conjugates, Journal of Materials Chemistry, vol.17, pp.1916-1922, 2007.

C. Boyer, V. Bulmus, J. Liu, T. P. Davis, M. H. Stenzel et al., Well-defined protein? polymer conjugates via in situ RAFT polymerization, Journal of the American Chemical Society, vol.129, pp.7145-7154, 2007.

Z. Liu, C. Dong, X. Wang, H. Wang, W. Li et al., Self-Assembled Biodegradable Protein-Polymer Vesicle as a Tumor-Targeted Nanocarrier, ACS applied materials & interfaces, vol.6, pp.2393-2400, 2014.

X. Liu and W. Gao, Situ Growth of Self-Assembled Protein-Polymer Nanovesicles for Enhanced Intracellular Protein Delivery. ACS applied materials & interfaces, 2017.

X. Huang, M. Li, D. C. Green, D. S. Williams, A. J. Patil et al., Interfacial assembly of protein-polymer nano-conjugates into stimulus-responsive biomimetic protocells, Nature communications, 2013.

D. W. Urry, T. Trapane, and K. Prasad, Phase-structure transitions of the elastin polypentapeptide-water system within the framework of composition-temperature studies, Biopolymers, vol.24, pp.2345-2356, 1985.

D. W. Urry, Physical chemistry of biological free energy transduction as demonstrated by elastic protein-based polymers, The Journal of Physical Chemistry B, vol.101, pp.11007-11028, 1997.

R. Petitdemange, E. Garanger, L. Bataille, W. Dieryck, K. Bathany et al., Selective tuning of elastin-like polypeptide properties via methionine oxidation, Biomacromolecules, vol.18, pp.544-550, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01449294

J. R. Kramer, R. Petitdemange, L. Bataille, K. Bathany, A. Wirotius et al., Quantitative Side-Chain Modifications of Methionine-Containing Elastin-Like Polypeptides as a Versatile Tool to Tune Their Properties, ACS Macro Letters, vol.4, pp.1283-1286, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01361956

R. Petitdemange, E. Garanger, L. Bataille, K. Bathany, B. Garbay et al., Tuning Thermoresponsive Properties of Cationic Elastin-like Polypeptides by Varying Counterions and Side-Chains, Bioconjugate chemistry, vol.28, pp.1403-1412, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01646801

L. Ayres, M. R. Vos, P. H. Adams, I. O. Shklyarevskiy, and J. Van-hest,

, Elastin-based side-chain polymers synthesized by ATRP, Macromolecules, vol.36, pp.5967-5973, 2003.

L. Ayres, K. Koch, P. H. Adams, and J. C. Van-hest, Stimulus responsive behavior of elastin-based side chain polymers, Macromolecules, vol.38, pp.1699-1704, 2005.

S. K. Roberts, A. Chilkoti, and L. A. Setton, Multifunctional thermally transitioning oligopeptides prepared by ring-opening metathesis polymerization, Biomacromolecules, vol.8, pp.2618-2621, 2007.

R. M. Conrad, R. H. Grubbs, and . Tunable, Temperature-Responsive Polynorbornenes with Side Chains Based on an Elastin Peptide Sequence, Angewandte Chemie International Edition, vol.48, pp.8328-8330, 2009.

C. Kojima, K. Irie, T. Luo, and K. L. Kiick, Noncovalent Modulation of the Inverse Temperature Transition and Self-Assembly of Elastin-b-Collagen-like Peptide Bioconjugates, Journal of the American Chemical Society, vol.100, issue.22, pp.15362-15365, 2013.

Y. Pu, L. Zhang, H. Zheng, B. He, and Z. Gu, Synthesis and Drug Release of StarShaped Poly (benzyl L-aspartate)-block-poly (ethylene glycol) Copolymers with POSS Cores, Macromolecular bioscience, vol.14, pp.289-297, 2014.

J. Shen, C. Chen, W. Fu, L. Shi, and Z. Li, Conformation-specific self-assembly of thermo-responsive poly (ethylene glycol)-b-polypeptide diblock copolymer, Langmuir, vol.29, pp.6271-6278, 2013.

H. Lee, J. B. Park, and J. Y. Chang, Synthesis of poly

H. Gao, Z. Hu, Q. Guan, Y. Liu, F. Zhu et al., Synthesis and thermoreversible gelation of coil-helical polyethylene-block-poly (?-benzyl-L-glutamate) diblock copolymer, /polypeptide/poly (D, L-lactide) copolymers and their nanoparticles, vol.49, pp.4923-4929, 2011.

A. C. Holley, J. G. Ray, W. Wan, D. A. Savin, C. L. Mccormick et al., pH-responsive HPMA-b-(l-Glu) copolymers synthesized via sequential aqueous RAFT and ringopening polymerizations, Biomacromolecules, vol.14, pp.3793-3799, 2013.

S. Waley and J. Watson, , 1949.

D. Ballard and C. Bamford, Reactions of N-carboxy-?-amino-acid anhydrides catalysed by tertiary bases, Journal of the Chemical Society, pp.381-387

J. Rodríguez-hernández and S. Lecommandoux, Reversible inside-out micellization of pH-responsive and water-soluble vesicles based on polypeptide diblock copolymers, Journal of the American Chemical Society, vol.127, pp.2026-2027, 2005.

E. P. Holowka, D. J. Pochan, T. J. Deming, J. Huang, C. Bonduelle et al., Biologically active polymersomes from amphiphilic glycopeptides, Journal of the American Chemical Society, vol.127, issue.32, pp.119-122, 2005.

K. K. Upadhyay, J. L. Meins, A. Misra, P. Voisin, V. Bouchaud et al., Biomimetic doxorubicin loaded polymersomes from hyaluronan-block-poly (?-benzyl glutamate) copolymers, Biomacromolecules, vol.10, pp.2802-2808, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00400384

C. Schatz, S. Louguet, J. F. Le-meins, and S. Lecommandoux, Polysaccharideblock-polypeptide Copolymer Vesicles: Towards Synthetic Viral Capsids, Angewandte Chemie International Edition, vol.48, pp.2572-2575, 2009.

K. K. Upadhyay, A. N. Bhatt, A. K. Mishra, B. S. Dwarakanath, S. Jain et al., The intracellular drug delivery and anti tumor activity of doxorubicin loaded poly (?-benzyl l-glutamate)-b-hyaluronan polymersomes, Biomaterials, vol.31, pp.2882-2892, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00652923

N. Hadjichristidis, H. Iatrou, M. Pitsikalis, and G. Sakellariou, Synthesis of welldefined polypeptide-based materials via the ring-opening polymerization of ?-amino acid Ncarboxyanhydrides, Chemical reviews, vol.109, pp.5528-5578, 2009.

J. Cheng and T. J. Deming, Synthesis of polypeptides by ring-opening polymerization of ?-amino acid N-carboxyanhydrides, In Peptide-based materials

J. Huang and A. Heise, Stimuli responsive synthetic polypeptides derived from Ncarboxyanhydride (NCA) polymerisation, Chemical Society Reviews, vol.42, pp.7373-7390, 2013.

G. J. Habraken, M. Peeters, C. H. Dietz, C. E. Koning, and A. Heise, How controlled and versatile is N-carboxy anhydride (NCA) polymerization at 0 C? Effect of temperature on homo-, block-and graft (co) polymerization, Polymer Chemistry, vol.1, pp.514-524, 2010.

W. Hanby, S. Waley, J. Watson, W. Vayaboury, O. Giani et al., Living Polymerization of ?-Amino Acid N-Carboxyanhydrides (NCA) upon Decreasing the Reaction Temperature, Macromolecular rapid communications, vol.25, issue.41, pp.1221-1224, 2004.

G. J. Habraken, K. H. Wilsens, C. E. Koning, and A. Heise, Optimization of Ncarboxyanhydride (NCA) polymerization by variation of reaction temperature and pressure, Polymer Chemistry, vol.2, pp.1322-1330, 2011.

H. Lu, J. Wang, Z. Song, L. Yin, Y. Zhang et al., Recent advances in amino acid N-carboxyanhydrides and synthetic polypeptides: chemistry, self-assembly and biological applications, Chemical Communications, vol.50, pp.139-155, 2014.

R. Nakamura, K. Aoi, M. Okada, F. Chécot, A. Brûlet et al., Controlled Synthesis of a Chitosan-Based Graft Copolymer Having Polysarcosine Side Chains Using the NCA Method with a Carboxylic Acid Additive, Macromolecular rapid communications, vol.27, pp.4308-4315, 2005.

A. Peyret, J. F. Trant, C. V. Bonduelle, K. Ferji, N. Jain et al., Synthetic glycopolypeptides: synthesis and self-assembly of poly (?-benzyl-Lglutamate)-glycosylated dendron hybrids, Polymer Chemistry, vol.6, pp.7902-7912, 2015.

C. Bonduelle, J. Huang, E. Ibarboure, A. Heise, and S. Lecommandoux, Synthesis and self-assembly of "tree-like" amphiphilic glycopolypeptides, Chemical communications, vol.48, pp.8353-8355, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00757834

E. Bradbury, C. Crane-robinson, L. Paolillo, and P. Temussi, Nmr studies of the helix-coil transition of polypeptides in non-protonating solvent mixtures, Polymer, vol.14, pp.303-308, 1973.

Y. Jeong, S. Seo, I. Park, H. Lee, I. Kang et al., Cellular recognition of paclitaxel-loaded polymeric nanoparticles composed of poly (?-benzyl Lglutamate) and poly (ethylene glycol) diblock copolymer endcapped with galactose moiety, International journal of pharmaceutics, vol.296, pp.151-161, 2005.

P. Heller, N. Mohr, A. Birke, B. Weber, A. Reske-kunz et al., Directed Interactions of Block Copolypept (o) ides with Mannose-binding Receptors: PeptoMicelles Targeted to Cells of the Innate Immune System, Macromolecular bioscience, vol.15, pp.63-73, 2015.

D. E. Discher and A. Eisenberg, Polymer vesicles, Science, vol.297, pp.967-973, 2002.

C. Lee, L. Lu, J. Chen, J. C. Garno, and D. Zhang, Crystallization-driven thermoreversible gelation of coil-crystalline cyclic and linear diblock copolypeptoids, ACS Macro Letters, vol.2, pp.436-440, 2013.

D. Kakkar, S. Mazzaferro, J. Thevenot, C. Schatz, A. Bhatt et al., Amphiphilic PEO-b-PBLG Diblock and PBLGb-PEO-b-PBLG Triblock Copolymer Based Nanoparticles: Doxorubicin Loading and In Vitro Evaluation, Macromolecular bioscience, vol.15, pp.124-137, 2015.

L. Zhang and A. Eisenberg, Thermodynamic vs kinetic aspects in the formation and morphological transitions of crew-cut aggregates produced by self-assembly of polystyrene-bpoly (acrylic acid) block copolymers in dilute solution, Macromolecules, vol.32, pp.2239-2249, 1999.

H. Cui, Z. Chen, S. Zhong, K. L. Wooley, and D. J. Pochan, Block copolymer assembly via kinetic control, Science, vol.317, pp.647-650, 2007.

R. Bleul, R. Thiermann, and M. Maskos, Techniques to control polymersome size, Macromolecules, vol.48, pp.7396-7409, 2015.

I. Dimitrov and H. Schlaad, Chemical Communications, pp.2944-2945, 2003.

J. F. Lutz, D. Schütt, and S. Kubowicz, Macromolecular rapid communications, vol.26, pp.23-28, 2005.