Dimerization of a highly unsymmetrical lutetium bisphthalocyanine in solution

Arnaud Mentec (1) , Annig Pondaven (1) , Jean-Michel Kerbaol (1) , Maurice L'Her (1)

1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique

A lutetium heteroleptic bisphthalocyanine, bearing 16 chlorine atoms on one of the two macrocyclic rings and 4 tBu groups on the second phthalocyanine unit, dimerizes in dichloromethane or toluene solutions under ambient conditions

Mots clés: Lutetium sandwich complexes; Heteroleptic bisphthalocyanines; Dimerization Solution

Domaines: Chimie inorganique; Chimie de coordination; Chimie organique; Chimie

Arnaud Mentec, Annig Pondaven, Jean-Michel Kerbaol, Maurice L'Her. Dimerization of a highly unsymmetrical lutetium bisphthalocyanine in solution. Inorganic Chemistry Communications, 2006, 9 (8), pp.810 - 813. ⟨10.1016/j.inoche.2006.05.005⟩. ⟨hal-01582972⟩