Highly Ordered Nanoring Arrays Formed by Templated Si-​Containing Triblock Terpolymer Thin Films

Karim Aissou 1, 2, * Muhammad Mumtaz 1, 2 Pierre Marcasuzaa 1, 2 Cyril Brochon 1, 2 Eric Cloutet 2, 1 Guillaume Fleury 1, 2 Georges Hadziioannou 1, 2
* Auteur correspondant
1 LCPO - Laboratoire de Chimie des Polymères Organiques
2 TEAM 4 LCPO
Abstract : In this work, the directed selfassembly of Si-​contg. triblock terpolymer chains ordered into nanoscale ring arrays has been reported. To produce long-​range ordered ring patterns, a solvent vapor annealing (SVA) methodol. was used to promote the mobility of the poly(1,​1-​dimethylsilacyclobutane)​block-​polystyrene-​block-​poly(Me methacrylate) (PDMSB-​b-​PS-​b-​PMMA or DSM) chains deposited on topog. patterned silica substrates. By using this strategy, highly ordered core​/shell cylinders with a domain orientation change induced by the film thickness were demonstrated. An effective control of the domain orientation was achieved by using a blending methodol., which revealed an efficient route to fabricate templated DSM thin films with core​/shell cylinders having a highly desired out-​of-​plane orientation both on mesas and in trenches.
Keywords : polymer interaction parameter nanorings self-assembly plastic films copolymer
Type de document :
Article dans une revue
Small, Wiley-VCH Verlag, 2017, 13 (12), pp.1603184. 〈10.1002/smll.201603184〉
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https://hal.archives-ouvertes.fr/hal-01452668
Contributeur : Eric Cloutet <>
Soumis le : jeudi 2 février 2017 - 10:19:12
Dernière modification le : jeudi 11 janvier 2018 - 06:28:09

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Karim Aissou, Muhammad Mumtaz, Pierre Marcasuzaa, Cyril Brochon, Eric Cloutet, et al.. Highly Ordered Nanoring Arrays Formed by Templated Si-​Containing Triblock Terpolymer Thin Films. Small, Wiley-VCH Verlag, 2017, 13 (12), pp.1603184. 〈10.1002/smll.201603184〉. 〈hal-01452668〉

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