Effect of the nanocrystallization on pure iron nitriding kinetics

Véronique Peres (1, 2, 3) , Victor Lacaille (4) , Guillaume Kermouche (1, 5, 6) , Constance Morel (7) , Jean-Michel Bergheau (4)

1 LGF-ENSMSE - Laboratoire Georges Friedel
2 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
3 PRESSIC-ENSMSE - Procédés et REactivité des Systèmes Solide-gaz, Instrumentation et Capteurs
4 LTDS - Laboratoire de Tribologie et Dynamique des Systèmes
5 SMS-ENSMSE - Centre Science des Matériaux et des Structures
6 PMM-ENSMSE- Département Physique et Mécanique des Matériaux
7 WINOA

Gas nitriding has been used to improve the mechanical properties and corrosion resistance of components made of steel. This thermochemical surface treatment is performed using a flowing NH₃, N₂ gas mixture. The gas nitriding is usually performed at a temperature between 500 to 580°C for typically durations of 20 to 80h which involve very long cycle times. A pre-treatment of the sample surface by shot peening can be applied to produce nanocrystalline grains. This surface treatment enhances the nitrogen diffusion. The purpose of our study is to investigate the effect of nanocrystallization of pure iron samples on nitriding kinetics. Pure iron samples obtained by cold crucible melting have been submitted to short duration or long duration NanoPeening® treatments. The samples are cuts in 5 mm thick pins in the cylindrical ingots (diameter 11 mm). Both sides of the pins receive the shot peening treatment. The pins are then cutted under water into 1 mm thick disks. The untreated surface is polished with SiC abrasive paper. For comparison, untreated shot peening iron disks (NG) are also prepared. The gas nitriding isothermal tests are performed at 500°C under NH₃, N₂, He mixture in a SETARAM TAG 24 thermobalance. The nitriding durations vary from 10 to 210 minutes. After the gas nitriding, the samples are first analysed by XRD. The nitrogen profiles are measured by GDOES (Glow Discharge Optical Emission Spectrometry). Finally, the machining and cross sectional electronics views of the samples are achieved in a FIB (Focused Ion Beam).

Mots clés: Nanocrystallization; gas nitriding; iron; nitriding kinetics; diffusion

Domaines: Génie des procédés

Véronique Peres, Victor Lacaille, Guillaume Kermouche, Constance Morel, Jean-Michel Bergheau. Effect of the nanocrystallization on pure iron nitriding kinetics. Dr B. Pint; Dr D. Monceau. HTCPM 2016 - 9th International Symposium on High-Temperature Corrosion and Protection of Materials, May 2016, Les Embiez, France. Springer, Oxidation of Metals - Edition Springer, pp.ID 116, 2017. ⟨hal-01427370⟩