Synthesis of a Novel Rhizobitoxine-Like Triazole-Containing Amino Acid

Abstract : The synthesis of the four stereoisomers of a new 1,2,3-tri-azole analogue of rhizobitoxine from serine is described. The key step is a Huisgen 1,3-dipolar cycloaddition on an ethynylglycine synthon.
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Thibaut Boibessot, David Bénimélis, Marion Jean, Zohra Benfodda, Patrick Meffre. Synthesis of a Novel Rhizobitoxine-Like Triazole-Containing Amino Acid. SYNLETT, Georg Thieme Verlag, 2016, 27 (19), pp.2685-2688. ⟨10.1055/s-0036-1588300⟩. ⟨hal-01404310⟩

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