A prototype reversible polymersome-stabilized H2S photoejector operating under pseudophysiological conditions

Abstract : Persistent self-assembled polymersome capsules are shown to solubilise and stabilize a new hydrosulfide-containing (2), as well as hydroxylated (1), malachite green derivatives in their leuco-forms in aqueous buffer solution. Photoirradiation resulted in reversible hydroxide release/hydrogen sulfide generation. Notably, the efficient augmentation of H2S concentration to physiologically-relevant levels is shown.
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https://hal.archives-ouvertes.fr/hal-01360809
Contributor : Dominique Richard <>
Submitted on : Tuesday, September 6, 2016 - 12:02:40 PM
Last modification on : Thursday, January 11, 2018 - 6:28:10 AM

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Arnaud Tron, Ariane Peyret, Julie Thevenot, Robin Bofinger, Sébastien Lecommandoux, et al.. A prototype reversible polymersome-stabilized H2S photoejector operating under pseudophysiological conditions. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2016, 14 (27), pp.6394-6397. ⟨10.1039/c6ob01155a ⟩. ⟨hal-01360809⟩

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