A Pt/Al2O3-supported metal-organic framework film as the size-selective core-shell hydrogenation catalyst

S. Aguado (1) , S. El-Jamal (2) , Frédéric Meunier (2) , J. Canivet (2) , D. Farrusseng (2)

1 IRCELYON - Institut de recherches sur la catalyse et l'environnement de Lyon
2 ING - IRCELYON-Ingéniérie, du matériau au réacteur

The substituted imidazolate-based MOF (SIM-1) easily forms a homogeneous layer at the surface of millimetric platinum-loaded alumina beads. This new core-shell SIM-1@Pt/Al2O3 catalyst shows the fine molecular sieving effect for the Pt-catalyzed hydrogenation of carbon-carbon double bonds.

Domaines: Catalyse; Environnement et Société

S. Aguado, S. El-Jamal, Frédéric Meunier, J. Canivet, D. Farrusseng. A Pt/Al2O3-supported metal-organic framework film as the size-selective core-shell hydrogenation catalyst. Chemical Communications, 2016, 52 (44), pp.7161-7163. ⟨10.1039/c6cc03096c⟩. ⟨hal-01336710⟩