Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials

S. Mishra (1) , Erwann Jeanneau , Marc Rolland (2) , S. Daniele (1)

1 CDURABLE - IRCELYON-C'Durable
2 IEM - Institut Européen des membranes

A new homoleptic iron(III) complex, [Fe-4(mdea)(6)]center dot 6CHCl(3) (mdeaH(2) = N-methyl diethanolamine), isolated in star-or chair-shaped isomeric forms, was evaluated and compared with other homoleptic iron(III) aminoalkoxides for different sol-gel parameters to stabilize nanosized colloidal suspensions, and to elaborate magnetic Fe2O3 and BiFeO3 nanoparticles as well as thin films by spin coating.

Domaines: Catalyse; Environnement et Société

S. Mishra, Erwann Jeanneau, Marc Rolland, S. Daniele. Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials. RSC Advances, 2016, 6 (3), pp.1738-1743. ⟨10.1039/c5ra24627j⟩. ⟨hal-01277440⟩