Nonstatistical fragmentation of large molecules

Abstract : We present experimental evidence for the dominance of prompt single-atom knockout in fragmenting collisions between large polycyclic aromatic hydrocarbon cations and He atoms at center-of-mass energies close to 100 eV. Such nonstatistical processes are shown to give highly reactive fragments. We argue that nonstatistical fragmentation is dominant for any sufficiently large molecular system under similar conditions.
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Submitted on : Tuesday, October 13, 2015 - 5:33:08 PM
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M. H. Stockett, H. Zettergren, L. Adoui, J. D. Alexander, U. Bērziņš, et al.. Nonstatistical fragmentation of large molecules. Physical Review A, American Physical Society, 2014, 89 (3), pp.032701. ⟨10.1103/PhysRevA.89.032701⟩. ⟨hal-01215250⟩



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