On the Riemannian structure of the residue curves maps

Nataliya Shcherbakova (1) , Vincent Gerbaud (1) , Ivonne Rodriguez-Donis (1)

1 LGC - Laboratoire de Génie Chimique

In this paper, we revise the structure of the residue curve maps (RCM) theory of simple evaporation from the point of view of Differential Geometry. RCM are broadly used for the qualitative analysis of distillation of multicomponent mixtures within the thermodynamic equilibrium model. Nevertheless, some of their basic properties are still a matter of discussion. For instance, this concerns the connection between RCM and the associated boiling temperature surface and the topological characterization of the distillation boundaries. In this paper we put in evidence the Riemannian metric hidden behind the thermodynamic equilibrium condition written in the form of the van der Waals–Storonkin equation, and we show that the differential equations of residue curves have formal gradient structure. We discuss the first non-trivial consequences ofthis factfor the RCM theory ofternary mixtures.

Mots clés: Residue curves; Gradient systems; Riemannian metric

Domaines: Génie chimique

Nataliya Shcherbakova, Vincent Gerbaud, Ivonne Rodriguez-Donis. On the Riemannian structure of the residue curves maps. Chemical Engineering Research and Design, 2015, vol. 99, pp. 87-96. ⟨10.1016/j.cherd.2015.05.029⟩. ⟨hal-01200753⟩