Mechanistic insight into the reduction of tertiary phosphine oxides by Ti(OiPr)4/TMDS

Abstract : The reduction mechanism of tertiary phosphine oxides by Ti(OiPr)4/hydrosiloxane was studied. Strong improvement was achieved using a drying agent. ESR spectra of the reaction mixture give evidence for a single electronic transfer (SET) mechanism.
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Journal articles
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https://hal.archives-ouvertes.fr/hal-01166157
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Submitted on : Monday, June 22, 2015 - 11:33:42 AM
Last modification on : Thursday, December 12, 2019 - 10:46:09 PM

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  • HAL Id : hal-01166157, version 1

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Christelle Petit, Alain Favre-Reguillon, Belen Albela, Laurent Bonneviot, Gerard Mignani, et al.. Mechanistic insight into the reduction of tertiary phosphine oxides by Ti(OiPr)4/TMDS. Organometallics, American Chemical Society, 2009, 28 (22), pp.6379-6382. ⟨hal-01166157⟩

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